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  Preparation of Allyl-, Alkenyl- and of Functionalized Arylmanganese Reagents by Oxidative Insertion of Manganese-Graphite into Organic Halides

Fürstner, A., & Brunner, H. (1996). Preparation of Allyl-, Alkenyl- and of Functionalized Arylmanganese Reagents by Oxidative Insertion of Manganese-Graphite into Organic Halides. Tetrahedron Letters, 37(39), 7009-7012. doi:10.1016/0040-4039(96)01591-2.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-079A-A Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-079B-8
Genre: Journal Article

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 Creators:
Fürstner, Alois1, Author              
Brunner, Heiko1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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 Abstract: Reduction of MnBr2·nLiBr (n = 1,2) with 2 C8K in THF affords highly active Mn-graphite, which readily inserts into allyl-, alkenyl-, (substituted) aryl- and heteroaryl halides. The functionalized organomanganese compounds thus obtained may be efficiently trapped with different electrophiles such as aldehydes, anhydrides and acid chlorides, or can be cross-coupled with alkenyl halides in the presence of catalytic amounts of Fe(acac)3.

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Language(s): eng - English
 Dates: 1996-09-23
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1016/0040-4039(96)01591-2
 Degree: -

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Title: Tetrahedron Letters
  Other : Tetrahedron Lett.
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: 4 Volume / Issue: 37 (39) Sequence Number: - Start / End Page: 7009 - 7012 Identifier: ISSN: 0040-4039
CoNE: /journals/resource/954925448772