Hexaaquoaluminum(III) as an environmental friendly activator of hydrogen 
peroxide for the catalytic epoxidation of cis-cyclooctene

Rinaldi, Roberto; Fujiwara, Fred Y.; Schuchardt, Ulf

doi:10.1016/j.catcom.2004.04.003

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Hexaaquoaluminum(III) as an environmental friendly activator of hydrogen peroxide for the catalytic epoxidation of cis-cyclooctene

Rinaldi, R., Fujiwara, F. Y., & Schuchardt, U. (2004). Hexaaquoaluminum(III) as an environmental friendly activator of hydrogen peroxide for the catalytic epoxidation of cis-cyclooctene. Catalysis Communications, 5(6), 333-337. doi:10.1016/j.catcom.2004.04.003.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-21B8-E Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-21B9-C

Genre: Journal Article

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Creators:
Rinaldi, Roberto^{1, 2}, Author
Fujiwara, Fred Y.², Author
Schuchardt, Ulf², Author

Affiliations:
1Research Group Rinaldi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445617
2Instituto de Quı́mica, Universidade Estadual de Campinas, P.O. Box 6154, 13084-971 Campinas-SP, Brazil, ou_persistent22

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Free keywords: Epoxidation; Hydrogen peroxide; Hexaaquoaluminum; cis-Cyclooctene

Abstract: A significant effort has been done towards the development of new catalysts for the synthesis of epoxides in a more environmental friendly way. We have found that a simple hexaaquoaluminum salt (2 mol% of Al(NO₃)₃ ·9 H₂O) is able to catalyze the epoxidation of cis-cyclooctene with high yields using aqueous (70 wt%) hydrogen peroxide. In THF we obtained 98% of conversion with 88% of selectivity for cyclooctene epoxide after 12 h.

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Language(s): eng - English

Dates: Published Online: 2004-05-06Date issued: 2004-06

Publication Status: Issued

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Rev. Type: Peer

Identifiers: DOI: 10.1016/j.catcom.2004.04.003

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Title: Catalysis Communications

Source Genre: Journal

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Publ. Info: Amsterdam : Elsevier

Pages: - Volume / Issue: 5 (6) Sequence Number: - Start / End Page: 333 - 337 Identifier: ISSN: 1566-7367
CoNE: https://pure.mpg.de/cone/journals/resource/110989848614006