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Schlagwörter:
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Zusammenfassung:
With hepta-1,6-diene and diallyl ether, Pd0 and Pt0 form highly reactive homoleptic dinuclear M2(1,6-diene)3 complexes, which are cleaved by donors L (e.g. C2H4, phos-phanes, phosphites, isonitriles) to afford mononuclear derivatives L–M(1,6-diene); the X-ray structure of (Me3P)Pd{(η2-CH2=CHCH2)2O} has been determined.