English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  NMR Investigation on the Solution Structure and Dynamic Behaviour of 1,2-Diphenyl-1,2-bis(trimethylsilyl)ethanediyldilithium

Fürstner, A., Seidel, G., Mons, H.-E., & Mynott, R. (1998). NMR Investigation on the Solution Structure and Dynamic Behaviour of 1,2-Diphenyl-1,2-bis(trimethylsilyl)ethanediyldilithium. European Journal of Inorganic Chemistry, (11), 1771-1774. doi:10.1002/(SICI)1099-0682(199811)1998:11<1771:AID-EJIC1771>3.0.CO;2-L.

Item is

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Fürstner, Alois1, Author              
Seidel, Günter1, Author              
Mons, Hans-Egbert2, Author
Mynott, Richard2, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Mynott (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445627              

Content

show
hide
Free keywords: Dianions; Organolithium compounds; Reductive metallation; HOESY; Lithium NMR
 Abstract: 1,2-Diphenyl-1,2-bis(trimethylsilyl)ethene (5) undergoes a smooth reductive metallation with metallic lithium to yield the corresponding dilithioethane derivative (Li2·5). The structure of this new compound in [D8]THF solution was determined by NMR spectroscopy (1H, 13C, 6Li, 7Li NMR and 6Li,1H-HOESY). It is shown that the phenyl rings have a high quinoid character and that the lithium cations are relatively mobile.

Details

show
hide
Language(s): eng - English
 Dates: 1998-06-061998-12-071998-11
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: European Journal of Inorganic Chemistry
  Other : Eur. J. Inorg. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: 4 Volume / Issue: (11) Sequence Number: - Start / End Page: 1771 - 1774 Identifier: ISSN: 1434-1948
CoNE: https://pure.mpg.de/cone/journals/resource/954926953810_1