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  An Al-Al One-Electron π Bond

Pluta, C., Pörschke, K.-R., Krüger, C., & Hildenbrand, K. (1993). An Al-Al One-Electron π Bond. Angewandte Chemie International Edition, 32(3), 388-390. doi:10.1002/anie.199303881.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-289C-B Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-289D-9
Genre: Journal Article

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 Creators:
Pluta, Christian1, Author
Pörschke, Klaus-Richard2, Author           
Krüger, Carl3, Author           
Hildenbrand, Knut1, Author
Affiliations:
1Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, DE, ou_1445580              
2Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445616              
3Service Department Krüger (XRAY), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445624              

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Free keywords: LEWIS ACIDITY; NICKEL(0); COMPLEXES; COMPOUND; ALUMINUM
 Abstract: Not a reductive rupture, but a strengthening of he result of the reduction of the dialane 1 with lithium. The salt isolated after addition of TMEDA contains the radical anion of 1, in which. as results of an X-ray structural analysis show, the Al-C bonds are distinctly longer (+ 0.06 angstrom) and the Al-Al bond considerably shorter (0.13 angstrom) than in 1 itself. These findings are in accord with results of MO calculations, which indicate a stabilization of the Al-Al bond by the additional electron.

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Language(s): eng - English
 Dates: 2003-12-221993-03
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.199303881
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie International Edition in English
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 32 (3) Sequence Number: - Start / End Page: 388 - 390 Identifier: Other: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/201310171