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  Dipole Chains in Zeolite Pores: The Effects of Symmetry Breaking

Marlow, F., Kornatowski, J., Reck, B., Hoffmann, K., & Caro, J. (1996). Dipole Chains in Zeolite Pores: The Effects of Symmetry Breaking. Molecular Crystals and Liquid Crystals Science and Technology Section A-Molecular Crystals and Liquid Crystals, 276(1-2), 295-304. doi:10.1080/10587259608039390.

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 Creators:
Marlow, Frank1, 2, Author              
Kornatowski, Jan3, 4, 5, Author              
Reck, B.6, Author
Hoffmann, K.1, Author
Caro, J.1, Author
Affiliations:
1Institut für Angewandte Chemie , Rudower Chaussee 5, D-12489, Berlin, ou_persistent22              
2Research Group Marlow, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445612              
3Faculty of Chemistry, N. Copernicus University , Gagarina 7, 87-100, Torun, Poland, ou_persistent22              
4Institut für Brennstoffchemie, RWTH Aachen , Worringerweg 1, D-52074, Aachen, Germany, ou_persistent22              
5Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              
6Bundesanstalt für Materialforschung und - prüfung , Rudower Chaussee 5, 12489, Berlin, Germany, ou_persistent22              

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 Abstract: Dipole molecules become arranged in a highly ordered manner within zeolite pores. They are oriented nearly parallel to the straight channels and aligned collectively into one specific direction. They form arrangements different from the crystallization in the free bulk as well as different from arrangements in amorphous hosts. This polar arrangement results in a lowering of the symmetry of the guest-host system compared to the host, nonlinear optical effects of second order such as second harmonic generation, a macroscopic polarization giving rise to pyroelectric effects and special phase transition phenomena in these one-dimensional systems.

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Language(s): eng - English
 Dates: 2006-10-041996
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1080/10587259608039390
 Degree: -

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Title: Molecular Crystals and Liquid Crystals Science and Technology Section A-Molecular Crystals and Liquid Crystals
Source Genre: Journal
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Publ. Info: Philadelphia : Gordon and Breach
Pages: - Volume / Issue: 276 (1-2) Sequence Number: - Start / End Page: 295 - 304 Identifier: ISSN: 1058-725X
CoNE: https://pure.mpg.de/cone/journals/resource/111056646394066