A “Hard/Soft” Mismatch Enables Catalytic Friedel−Crafts Acylations

Fürstner, Alois; Voigtländer, David; Schrader, Wolfgang; Giebel, Dirk; Reetz, Manfred T.

doi:10.1021/ol0069251

Local TagsRelease HistoryDetailsSummary

A “Hard/Soft” Mismatch Enables Catalytic Friedel−Crafts Acylations

Fürstner, A., Voigtländer, D., Schrader, W., Giebel, D., & Reetz, M. T. (2001). A “Hard/Soft” Mismatch Enables Catalytic Friedel−Crafts Acylations. Organic Letters, 3(3), 417-420. doi:10.1021/ol0069251.

Item is Released

show all hide all

Basic

show hide

Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-3B01-E Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-3B02-C

Genre: Journal Article

Files

show Files

Locators

show

Creators

show

hide

Creators:
Fürstner, Alois¹, Author
Voigtländer, David¹, Author
Schrader, Wolfgang², Author
Giebel, Dirk³, Author
Reetz, Manfred T.³, Author

Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584
2Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445629
3Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445588

Content

show

hide

Free keywords: -

Abstract: Cationic complexes of Pt(II) and other late transition metals efficiently catalyze Friedel−Crafts acylations of moderately activated arenes by carboxylic acid anhydrides. The nature of the catalytically relevant species formed from (PhCN)₂PtCl₂ and AgSbF₆ and their interactions with the substrates are studied by NMR and ESI-MS.

Details

show

hide

Language(s): eng - English

Dates: Submitted: 2000-11-27Published Online: 2001-01-17Date issued: 2001-02-08

Publication Status: Issued

Pages: 4

Publishing info: -

Table of Contents: -

Rev. Type: Peer

Identifiers: DOI: 10.1021/ol0069251

Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show

hide

Title: Organic Letters

Other : Org. Lett.

Source Genre: Journal

Creator(s):

Affiliations:

Publ. Info: Washington, DC : American Chemical Society

Pages: 4 Volume / Issue: 3 (3) Sequence Number: - Start / End Page: 417 - 420 Identifier: ISSN: 1523-7060
CoNE: https://pure.mpg.de/cone/journals/resource/954925626338