Temperature-dependent spectral spin diffusion in solid state deuteron magnetic 
resonance

Müller, Andreas; Haeberlen, Ulrich

doi:10.1016/0009-2614(95)01309-1

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Temperature-dependent spectral spin diffusion in solid state deuteron magnetic resonance

Müller, A., & Haeberlen, U. (1996). Temperature-dependent spectral spin diffusion in solid state deuteron magnetic resonance. Chemical Physics Letters, 248: 3-4, pp. 249-254. doi:10.1016/0009-2614(95)01309-1.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-34A7-E Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-34A8-C

Genre: Journal Article

Alternative Title : Temperature-dependent spectral spin diffusion in solid state deuteron magnetic resonance

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Creators:
Müller, Andreas¹, Author
Haeberlen, Ulrich¹, Author

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1Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society, ou_1497739

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Abstract: The polarization transfer from the para to the ortho/meta deuterons was investigated in a single crystal of perdeuterated biphenyl, C12D10. It is demonstrated that this process is due to spin diffusion via dipolar coupling. We found that in the range from 290 to 315 K it is strongly dependent on the temperature. The apparent activation energy of about 75 kJ/mol is the same as that of the known 180° flips of phenyl rings about the long molecular axis. As an explanation of the observed temperature dependence of the spin diffusion we discuss an exchange broadening of the relevant zero−quantum line caused by the 180° flips

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Language(s): eng - English

Dates: Submitted: 1995-08-07Date issued: 1996-01-12

Publication Status: Issued

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Rev. Type: Peer

Identifiers: eDoc: 665240
DOI: 10.1016/0009-2614(95)01309-1
URI: www.sciencedirect.com/science?_ob%3DArticleURL%26_udi%3DB6TFN-3TJ5JRM-P%26_user%3D41901%26_coverDate%3D01%252F12%252F1996%26_rdoc%3D20%26_fmt%3Dsummary%26_orig%3Dbrowse%26_srch%3Ddoc-info%28%2523toc%25235231%25231996%2523997519996%252318466%2523FLP%2523display%2523Volume%29%26_cdi%3D5231%26_sort%3Dd%26_docanchor%3D%26view
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Title: Chemical Physics Letters

Other : Chem. Phys. Lett.

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Publ. Info: Amsterdam : North-Holland

Pages: - Volume / Issue: 248 Sequence Number: 3-4 Start / End Page: 249 - 254 Identifier: ISSN: 0009-2614
CoNE: https://pure.mpg.de/cone/journals/resource/954925389241