English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Exploiting the Reversibility of Olefin Metathesis. Syntheses of Macrocyclic Trisubstituted Alkenes and (R,R)-(−)-Pyrenophorin

Fürstner, A., Thiel, O. R., & Ackermann, L. (2001). Exploiting the Reversibility of Olefin Metathesis. Syntheses of Macrocyclic Trisubstituted Alkenes and (R,R)-(−)-Pyrenophorin. Organic Letters, 3(3), 449-451. doi:10.1021/ol0069554.

Item is

Files

show Files
hide Files
:
[129]SI.pdf (Supplementary material), 63KB
Name:
[129]SI.pdf
Description:
Supporting Information
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Fürstner, Alois1, Author              
Thiel, Oliver R.1, Author              
Ackermann, Lutz1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

Content

show
hide
Free keywords: -
 Abstract: The formation of the trisubstituted cycloalkene 7 by RCM of diene 5 proceeds via the acyclic dimer 6, thus demonstrating the ready reversibility of olefin metathesis if catalyzed by “second generation” ruthenium carbene complexes such as 2−4. When applied to acrylate 11, these catalysts trigger a cyclooligomerization process that evolves with time and serves as key step en route to the lactide antibiotic (−)-pyrenophorin 8.

Details

show
hide
Language(s): eng - English
 Dates: 2000-12-042001-01-122001-02-08
 Publication Status: Published in print
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ol0069554
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Organic Letters
  Other : Org. Lett.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Washington, DC : American Chemical Society
Pages: 3 Volume / Issue: 3 (3) Sequence Number: - Start / End Page: 449 - 451 Identifier: ISSN: 1523-7060
CoNE: https://pure.mpg.de/cone/journals/resource/954925626338