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  Dynamic properties of solid basketene as studied by deuterium and proton NMR

Müller, A., Zimmermann, H., Haeberlen, U., Wolff, J. J., Poupko, R., & Luz, Z. (1996). Dynamic properties of solid basketene as studied by deuterium and proton NMR. The Journal of Physical Chemistry, 100(33), 13911-13913. doi:10.1021/jp9603896.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-34B8-8 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-34B9-6
Genre: Journal Article
Alternative Title : Dynamic properties of solid basketene as studied by deuterium and proton NMR

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JPhysChem_100_1996_13911.pdf (Any fulltext), 173KB
 
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 Creators:
Müller, Andreas1, Author              
Zimmermann, Herbert2, 3, Author              
Haeberlen, Ulrich1, Author              
Wolff, J. J., Author
Poupko, Raphy, Author
Luz, Zeev, Author
Affiliations:
1Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society, ou_1497739              
2Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
3Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              

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 Abstract: Deuterium and proton NMR line shape and T1 relaxation measurements of solid basketene-d2 are reported. The compound is polymorphic, exhibiting a low-temperature rigid phase that transforms at 221 K to a plastic phase. Kinetic parameters for the molecular reorientation and self-diffusion in the high-temperature phase are derived, yielding the Arrhenius law parameters A = 4 × 1013 s-1, E = (13.8 ± 0.5) kJ mol-1 for reorientation and Ad=1.2 × 1013 s-1, Ed = (39 ± 2) kJ mol-1 for self-diffusion

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Language(s): eng - English
 Dates: 1996-05-301996-02-081996-05-301996-08-15
 Publication Status: Published in print
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 Rev. Method: Peer
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Title: The Journal of Physical Chemistry
Source Genre: Journal
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Publ. Info: Washington DC : American Chemical Society
Pages: - Volume / Issue: 100 (33) Sequence Number: - Start / End Page: 13911 - 13913 Identifier: ISSN: 0022-3654
ISSN: 0092-7325