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  Synthesis, Solid-State Structure, and Electronic Nature of a Phosphinine-Stabilized triangulo Palladium Cluster

Reetz, M. T., Bohres, E., Goddard, R., Holthausen, M. C., & Thiel, W. (1999). Synthesis, Solid-State Structure, and Electronic Nature of a Phosphinine-Stabilized triangulo Palladium Cluster. Chemistry - A European Journal, 5(7), 2101-2108. doi:10.1002/(SICI)1521-3765(19990702)5:7<2101:AID-CHEM2101>3.0.CO;2-0.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-3AF5-1 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-3AF6-0
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Bohres, Edward1, Author
Goddard, Richard2, Author           
Holthausen, Max C.3, Author
Thiel, Walter3, Author           
Affiliations:
1Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445588              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
3Organisch-chemisches Institut, Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland, ou_persistent22              

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Free keywords: Cluster compounds; Density functional calculations; MO interactions; P ligands; Palladium
 Abstract: An unusual structure is found for a novel triangulo palladium cluster, stabilized by 2,4,6-triphenylphosphine and triethylphosphane (see figure; large open circles: Pd, small hashed circles: P, small open circles: C). The bonding involving phosphinine bridges between two Pd atoms is based on σ and π orbital interactions, as demonstrated by quantum-mechanical calculations of a model compound.

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Language(s): eng - English
 Dates: 1998-11-181999-06-241999-07-02
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/(SICI)1521-3765(19990702)5:7<2101::AID-CHEM2101>3.0.CO;2-0
 Degree: -

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Title: Chemistry - A European Journal
  Other : Chem. Eur. J.
Source Genre: Journal
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Publ. Info: Weinheim, Germany : VCH Verlagsgesellschaft
Pages: 8 Volume / Issue: 5 (7) Sequence Number: - Start / End Page: 2101 - 2108 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058