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  Phosphoric Acid Based Heterodimers in Asymmetric Catalysis

Monaco, M. R., Pupo, G., & List, B. (2016). Phosphoric Acid Based Heterodimers in Asymmetric Catalysis. Synlett, 27(7), 1027-1040. doi:10.1055/s-0035-1561954.

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 Creators:
Monaco, Mattia R.1, Author              
Pupo, Gabriele1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: phosphoric acids; non-covalent catalysis; heterodimeric self-assembly; carboxylic acids; enol catalysis; branched ketones
 Abstract: Chiral phosphoric acid diesters arguably constitute the most exploited class of catalysts in asymmetric Brønsted acid catalysis. Despite being highly investigated for their acidic properties, these compounds display an amphoteric nature, which has instead been considerably overlooked. The potential of this dichotomous polarity has recently been disclosed and applied to the development of novel reaction modes in organocatalysis. In this account, we present our recent advances in this area, focusing on the establishment of heterodimeric interactions toward the nucleophilic activation of carboxylic acids, thiocarboxylic acids and ketones (via their enols) in asymmetric transformations.

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Language(s): eng - English
 Dates: 2016-03-092016-03-292016-04-01
 Publication Status: Published in print
 Pages: 14
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0035-1561954
 Degree: -

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Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
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Affiliations:
Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 27 (7) Sequence Number: - Start / End Page: 1027 - 1040 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856