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  Towards High-Performance Lewis Acid Organocatalysis

Ratjen, L., van Gemmeren, M., Pesciaioli, F., & List, B. (2014). Towards High-Performance Lewis Acid Organocatalysis. Angewandte Chemie International Edition, 53(33), 8765-8769. doi:10.1002/anie.201402765.

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 Creators:
Ratjen, Lars1, Author              
van Gemmeren, Manuel1, Author              
Pesciaioli, Fabio1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: catalyst design; disulfonimides; Lewis acids; organocatalysis; silylium ions
 Abstract: The combination of Lewis acid organocatalysis and internal hydrogen-bond assistance was used to develop a new type of highly active disulfonimide catalyst. The increased Lewis acidity was documented by activity comparisons as well as theoretical investigations. Finally, the potential of the hydrogen-bond-assisted disulfonimide catalyst was demonstrated by its application in an enantioselective transformation.

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Language(s): eng - English
 Dates: 2014-05-062014-08-11
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201402765
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 53 (33) Sequence Number: - Start / End Page: 8765 - 8769 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851