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  Tetrameres Lithium-tris(N, N-dimethylamino)silylamid: Synthese, Struktur und Reaktivität. Tetrameric Lithium Tris(N,N-dimethylamino)silylamide: Synthesis, Structure, and Reactivity

Walther, D., Schramm, F., Theyssen, N., Beckert, R., & Görls, H. (2002). Tetrameres Lithium-tris(N, N-dimethylamino)silylamid: Synthese, Struktur und Reaktivität. Tetrameric Lithium Tris(N,N-dimethylamino)silylamide: Synthesis, Structure, and Reactivity. Zeitschrift für anorganische und allgemeine Chemie, 628(9-10), 1938-1940. doi:10.1002/1521-3749(200209)628:9/10<1938:AID-ZAAC1938>3.0.CO;2-8.

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 Creators:
Walther, Dirk1, Author
Schramm, Frank1, Author
Theyssen, Nils1, 2, Author           
Beckert, R.1, Author
Görls, Helmar1, Author
Affiliations:
1Institut für Anorg. und Analyt. Chemie der Universität Jena, August-Bebel-Straße 2, D-07743 Jena, Fax (internat) +49-(0)3641948102, ou_persistent22              
2Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445632              

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Free keywords: Lithium; Silicon; Amide; Crystal structure
 Abstract: [(Me2N)3SiNHLi]4 (1) has been prepared from (Me2N)3Si—NH2 and t-BuLi. According to the crystal structure analysis 1 has a laddering structure consisting of seven four-membered rings. The two Li2(NH)2 units contain three-coordinated Li; the other five rings consist of Li(NH)2Si units in which the Li atoms are found to be four-coordinated. Reaction with bis(4-tolyl)-oxalic imidoyl chloride results in the formation of bis(N, N′-dimethylamino)-bis(4-tolyl)oxalamidine and two new heterocycles.

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Language(s): eng - English
 Dates: 2002-09-202002-09
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Zeitschrift fuer Anorganische und Allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : WILEY-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 628 (9-10) Sequence Number: - Start / End Page: 1938 - 1940 Identifier: ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895