English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Nickel(I)-Komplexe mit 1,1′-Bis(phosphino)ferrocenen als Liganden

Langer, J., Fischer, R., Görls, H., Theyssen, N., & Walther, D. (2007). Nickel(I)-Komplexe mit 1,1′-Bis(phosphino)ferrocenen als Liganden. Zeitschrift für anorganische und allgemeine Chemie, 633(4), 557-562. doi:10.1002/zaac.200600350.

Item is

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Langer, Jens1, Author
Fischer, Reinald1, Author
Görls, Helmar1, Author
Theyssen, Nils1, 2, Author              
Walther, Dirk1, Author
Affiliations:
1Institut für Anorganische und Analytische Chemie der Universität Jena, Lessingstraße 8, D-07743 Jena, Fax: (+49) (0)3641 948102, ou_persistent22              
2Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445632              

Content

show
hide
Free keywords: Nickel; Phosphines; Crystal structure; EPR spectroscopy
 Abstract: Nickel(I) Complexes with 1,1′-Bis(phosphino)ferrocenes as Ligands. The thermically stable monomeric Nickel(I) complexes [(dtbpf)Ni(acac)] (1) and [(dippf)NiCl] (2) were synthesized and characterized by elemental analyses, EPR spectroscopy, and by X-ray crystal structure analyses of single crystals (dtbpf: 1,1′-bis(di-tertbutylphosphino)ferrocene; dippf: 1,1′-bis(diisopropylphosphino)ferrocene). 1 is formed by reduction of Ni(acac)2 with triethylaluminium in the presence of dtbpf, together with the nickel(0) complex [(dtbpf)Ni(C2H4)]. 1 contains a NiI atom surrounded of two O- and two P donor atoms in a distorted tetrahedral coordination. 2 was obtained by reduction of [(dippf)NiCl2] with NaBH4. In 2 the nickel(I) atom adopts trigonal planar coordination.

Details

show
hide
Language(s): eng - English
 Dates: 2007-03-072007-04
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/zaac.200600350
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Zeitschrift fuer Anorganische und Allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : WILEY-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 633 (4) Sequence Number: - Start / End Page: 557 - 562 Identifier: ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895