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  Iron-Catalyzed Cross-Coupling Reactions of Alkyl-Grignard Reagents with Aryl Chlorides, Tosylates, and Triflates

Fürstner, A., & Leitner, A. (2002). Iron-Catalyzed Cross-Coupling Reactions of Alkyl-Grignard Reagents with Aryl Chlorides, Tosylates, and Triflates. Angewandte Chemie International Edition, 41(4), 609-612. doi:10.1002/1521-3773(20020215)41:4<609:AID-ANIE609>3.0.CO;2-M.

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 Creators:
Fürstner, A.1, Author              
Leitner, A.1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: cross-coupling; Grignard reagents; iron; magnesium; organometallic compounds
 Abstract: Aryl chlorides are better substrates than the corresponding bromides or iodides in the presented cross-coupling with alkyl Grignard reagents that is catalyzed by iron salts (see scheme); even aryl tosylates are converted efficiently. This situation is attributed to a novel catalytic cycle, which probably involves iron complexes with formally negative oxidation states (probably Fe−II).

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Language(s): eng - English
 Dates: 2001-10-122002-02-142002-02-15
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag
Pages: 4 Volume / Issue: 41 (4) Sequence Number: - Start / End Page: 609 - 612 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833