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  Zur Lewisacidität von Nickel(0): VII. Alkalimetall-μ3-hydrido-tetrakis(ethen)diniccolat(0)-Komplexe: (pmdta) Li(μ3-H)Ni2(C2H4)4 und (pmdta)Na(μ3-H)Ni2(C2H4)4

Pörschke, K.-R., & Wilke, G. (1988). Zur Lewisacidität von Nickel(0): VII. Alkalimetall-μ3-hydrido-tetrakis(ethen)diniccolat(0)-Komplexe: (pmdta) Li(μ3-H)Ni2(C2H4)4 und (pmdta)Na(μ3-H)Ni2(C2H4)4. Journal of Organometallic Chemistry, 349(1-2), 257-261. doi:10.1016/0022-328X(88)80455-8.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-655F-B Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-6560-5
Genre: Journal Article

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 Creators:
Pörschke, Klaus-Richard1, Author           
Wilke, Günther2, Author           
Affiliations:
1Research Group Pörschke, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445616              
2Research Department Wilke, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445591              

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 Abstract: Ni(C2H4)3 reacts with alkalimetal hydridoaluminates or -gallates MAHAl/GaR3 and MAH2AlR2 (R= alkyl) in ether/pmdta at temperatures between −70 and −20°C to yield the ion pair complexes (pmdta)MA(μ3-H)Ni2(C2H4)2 (MA = Li (2a), Na (2b)). According to their structure and chemical properties, 2a,b can be regarded as model compounds for the nickel(0) induced addition of alkalimetal hydrides to alkenes.

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Language(s): deu - German
 Dates: 1986-09-161988-07-19
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0022-328X(88)80455-8
 Degree: -

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Title: Journal of Organometallic Chemistry
  Other : J. Organomet. Chem.
Source Genre: Journal
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Publ. Info: Lausanne, Schweiz : Elsevier Science
Pages: - Volume / Issue: 349 (1-2) Sequence Number: - Start / End Page: 257 - 261 Identifier: ISSN: 0022-328X
CoNE: https://pure.mpg.de/cone/journals/resource/954925622228