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  Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

David, B., Monkowius, U., Rust, J., Lehmann, C. W., Hyzak, L., & Mohr, F. (2014). Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl. Dalton Transactions, 43(28), 11059-11066. doi:10.1039/C4DT00778F.

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 Creators:
David, B.1, Author
Monkowius, U.2, Author
Rust, J.3, Author              
Lehmann, C. W.3, Author              
Hyzak, L.1, Author
Mohr, F.3, Author
Affiliations:
1Fachbereich C, Anorganische Chemie, Bergische Universität Wuppertal, Gaußstraße 20, 42119 Wuppertal, Germany, ou_persistent22              
2Institut für Anorganische Chemie, Johannes Kepler University Linz, Altenbergerstraße 69, 4040 Linz, Austria, ou_persistent22              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: An oligomeric gold(III) compound containing dicarbanionic chelating 4,4′-di-tert-butylbiphenyl was prepared via transmetallation using the corresponding organotin(IV) compound. The reactivity of the chloro-bridged oligomer with various species including neutral N-, P-, and C-donor ligands as well as monoanionic S- and Se-ligands was investigated. Some of the products were characterised by X-ray crystallography. The photophysical properties of two derivatives were studied.

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Language(s): eng - English
 Dates: 2014-03-142014-05-232014-05-272014-07-28
 Publication Status: Published in print
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C4DT00778F
 Degree: -

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Title: Dalton Transactions
  Abbreviation : Dalton Trans.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 43 (28) Sequence Number: - Start / End Page: 11059 - 11066 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323