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  Preparation of anionic clathrate-II K24-xGe136 by filling of Ge(cF136)

Böhme, B., Reibold, M., Auffermann, G., Lichte, H., Baitinger, M., & Grin, Y. (2014). Preparation of anionic clathrate-II K24-xGe136 by filling of Ge(cF136). Zeitschrift für Kristallographie: International Journal for Structural, Physical, and Chemical Aspects of Crystalline Materials, 229(10), 677-686. doi:10.1515/zkri-2014-1764.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-9B46-3 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-9B47-1
Genre: Journal Article

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 Creators:
Böhme, B.1, Author              
Reibold, Marianne2, Author
Auffermann, Gudrun3, Author              
Lichte, Hannes2, Author
Baitinger, Michael4, Author              
Grin, Yuri5, Author              
Affiliations:
1Bodo Böhme, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863408              
2External Organizations, ou_persistent22              
3Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863432              
4Michael Baitinger, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863416              
5Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              

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 Abstract: Metastable Ge(cF136) with empty clathrate-II crystal structure was successfully used for the preparation of otherwise hardly accessible germanium clathrate phases. On reaction of Ge(cF136) with potassium vapour at 280 degrees C for 6 days, the new clathrate-II phase K24Ge136 was formed, in which the cages of the germanium framework are completely filled by potassium atoms. The crystal structure of KxGe136 is discussed for different potassium contents (x = 0, 8.6, 24).

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Language(s): eng - English
 Dates: 2014-09-182014-09-20
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000344727100001
DOI: 10.1515/zkri-2014-1764
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Title: Zeitschrift für Kristallographie: International Journal for Structural, Physical, and Chemical Aspects of Crystalline Materials
  Other : Z. Kristallogr.
Source Genre: Journal
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Publ. Info: München : Oldenbourg Wissenschaftsverlag
Pages: - Volume / Issue: 229 (10) Sequence Number: - Start / End Page: 677 - 686 Identifier: ISSN: 0044-2968
CoNE: /journals/resource/110978984076855_1