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  A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity

Wang, F., Mielby, J., Richter, F. H., Wang, G., Prieto, G., Kasama, T., et al. (2014). A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity. Angewandte Chemie International Edition, 53(33), 8645-8648. doi:10.1002/anie.201404912.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-A80F-F Version Permalink: https://hdl.handle.net/21.11116/0000-0007-5CB3-8
Genre: Journal Article

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 Creators:
Wang, Feng1, Author           
Mielby, Jerrik2, Author
Richter, Felix Herrmann1, Author           
Wang, Guanghui3, Author
Prieto, Gonzalo4, Author           
Kasama, Takeshi5, Author
Weidenthaler, Claudia6, Author           
Bongard, Hans-Josef7, Author           
Kegnæs, Søren2, Author
Fürstner, Alois8, Author           
Schüth, Ferdi1, Author           
Affiliations:
1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              
2Department of Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark), ou_persistent22              
3Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr (Germany), ou_persistent22              
4Research Group Prieto, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2243639              
5Center for Electron Nanoscopy, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark), ou_persistent22              
6Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1950291              
7Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
8Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: cross-coupling; nanoparticles; polymer supports; polyphenylenes
 Abstract: We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.

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Language(s): eng - English
 Dates: 2014-05-022014-07-152014-08-11
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201404912
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 53 (33) Sequence Number: - Start / End Page: 8645 - 8648 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851