English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Elementary Steps of Gold Catalysis: NMR Spectroscopy Reveals the Highly Cationic Character of a "Gold Carbenoid"

Seidel, G., Mynott, R., & Fürstner, A. (2009). Elementary Steps of Gold Catalysis: NMR Spectroscopy Reveals the Highly Cationic Character of a "Gold Carbenoid". Angewandte Chemie International Edition, 48(14), 2510-2513. doi:10.1002/anie.200806059.

Item is

Files

show Files
hide Files
:
anie_200806059_sm_miscellaneous_information.pdf (Supplementary material), 39KB
Name:
anie_200806059_sm_miscellaneous_information.pdf
Description:
Supporting Information
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
2009
Copyright Info:
Wiley-VCH, 69451 Weinheim, Germany
License:
-

Locators

show

Creators

show
hide
 Creators:
Seidel, Günter1, Author           
Mynott, Richard2, Author           
Fürstner, Alois1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Mynott (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445627              

Content

show
hide
Free keywords: carbenes; carbocations; gold; homogeneous catalysis; reactive intermediates
 Abstract: What are you? Even though the metal-induced ring opening of 3,3-disubstituted cyclopropenes is known to serve as a genuine carbene generator, the use of AuI in this reaction leads to a reactive intermediate with highly cationic character. This result has important implications for gold catalysis in general, which in the past has been commonly attributed to the intervention of gold carbenes.

Details

show
hide
Language(s): eng - English
 Dates: 2008-12-122009-02-262009-03-23
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200806059
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH Verlag
Pages: - Volume / Issue: 48 (14) Sequence Number: - Start / End Page: 2510 - 2513 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833