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  Elementary Steps of Gold Catalysis: NMR Spectroscopy Reveals the Highly Cationic Character of a "Gold Carbenoid"

Seidel, G., Mynott, R., & Fürstner, A. (2009). Elementary Steps of Gold Catalysis: NMR Spectroscopy Reveals the Highly Cationic Character of a "Gold Carbenoid". Angewandte Chemie International Edition, 48(14), 2510-2513. doi:10.1002/anie.200806059.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-C2F5-6 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-C2F6-4
Genre: Journal Article

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anie_200806059_sm_miscellaneous_information.pdf (Supplementary material), 39KB
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https://hdl.handle.net/11858/00-001M-0000-0024-C2F7-2
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anie_200806059_sm_miscellaneous_information.pdf
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Supporting Information
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Copyright Date:
2009
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Wiley-VCH, 69451 Weinheim, Germany
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 Creators:
Seidel, Günter1, Author           
Mynott, Richard2, Author           
Fürstner, Alois1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Mynott (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445627              

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Free keywords: carbenes; carbocations; gold; homogeneous catalysis; reactive intermediates
 Abstract: What are you? Even though the metal-induced ring opening of 3,3-disubstituted cyclopropenes is known to serve as a genuine carbene generator, the use of AuI in this reaction leads to a reactive intermediate with highly cationic character. This result has important implications for gold catalysis in general, which in the past has been commonly attributed to the intervention of gold carbenes.

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Language(s): eng - English
 Dates: 2008-12-122009-02-262009-03-23
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200806059
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag
Pages: - Volume / Issue: 48 (14) Sequence Number: - Start / End Page: 2510 - 2513 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833