English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Carbenes Stabilized by Ylides: Pushing the Limits

Fürstner, A., Alcarazo, M., Radkowski, K., & Lehmann, C. W. (2008). Carbenes Stabilized by Ylides: Pushing the Limits. Angewandte Chemie International Edition, 47(43), 8302-8306. doi:10.1002/anie.200803200.

Item is

Files

show Files
hide Files
:
z803200_s.pdf (Supplementary material), 202KB
Name:
z803200_s.pdf
Description:
Supporting Information
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
2008
Copyright Info:
Wiley-VCH, 69451 Weinheim, Germany
License:
-

Locators

show

Creators

show
hide
 Creators:
Fürstner, Alois1, Author           
Alcarazo, Manuel2, Author           
Radkowski, Karin1, Author           
Lehmann, Christian W.3, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

Content

show
hide
Free keywords: carbenes; heterocycles; ligands; rhodium; ylides
 Abstract: Being neighborly: The concept of placing two reactive intermediates next to each other to gain stability is borne out in amino(ylide)carbenes (AYCs). Different kinds of ylides stabilize an adjacent singlet carbene by donation of electron density from the ylidic carbon atom into the empty p orbital to give AYCs of various structural formats (see picture) that are distinguished by their exceptionally strong σ-donor qualities.

Details

show
hide
Language(s): eng - English
 Dates: 2008-07-022008-09-222008-10-13
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200803200
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 47 (43) Sequence Number: - Start / End Page: 8302 - 8306 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851