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  Coordination Chemistry of Ene-1,1-diamines and a Prototype "Carbodicarbene"

Fürstner, A., Alcarazo, M., Goddard, R., & Lehmann, C. W. (2008). Coordination Chemistry of Ene-1,1-diamines and a Prototype "Carbodicarbene". Angewandte Chemie International Edition, 47(17), 3210-3214. doi:10.1002/anie.200705798.

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z705798_s.pdf (Supplementary material), 128KB
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z705798_s.pdf
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Supporting Information
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Copyright Date:
2008
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Wiley-VCH, 69451 Weinheim, Germany
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 Creators:
Fürstner, Alois1, Author           
Alcarazo, Manuel2, Author           
Goddard, Richard3, Author           
Lehmann, Christian W.3, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: allenes; carbenes; enamines; gold; ylides
 Abstract: Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A series of stable ylid- or enolate gold complexes of ene-1,1-diamines not only emulate this property, but also reveal the exceptional donor capacity of such electron-rich olefin ligands. Moreover, the first metal complex of a tetraaminoallene is reported, which features a prototype “carbodicarbene” ligand bound to a transition-metal template.

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Language(s): eng - English
 Dates: 2007-12-182008-03-172008-04-14
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200705798
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 47 (17) Sequence Number: - Start / End Page: 3210 - 3214 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851