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  Unexpected molecular flip in solid-state photodimerization.

Thekku Veedu, S., Deng-Ke, C., Lavy, T., Botoshansky, M., & Menahem, K. (2013). Unexpected molecular flip in solid-state photodimerization. Crystal Growth and Design, 13(2), 936-941. doi:10.1021/cg3016707.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-B687-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0028-E5B4-8
Genre: Journal Article

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http://pubs.acs.org/doi/pdf/10.1021/cg3016707 (Publisher version)
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 Creators:
Thekku Veedu, S.1, Author              
Deng-Ke, C., Author
Lavy, T., Author
Botoshansky, M., Author
Menahem, K., Author
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: Three cocrystals of the light-stable compound 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol (I) with light-sensitive molecules 1,2-dimethyl-2(1H)-pyridinone (a), 6-methyl-2(1H)-pyridinone (b), and 2-methyl-2(1H)-pyridinone (c) were exposed to UV light. The light-sensitive molecules undergo molecular flip. The estimated activation energy of the flip is 9.72 kJ/mol. The kinetics of the reaction of I-c was studied showing sigmoidal behavior with Avrami exponent of n = 0.95(6), suggesting homogeneous reaction.

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Language(s): eng - English
 Dates: 2013-01-07
 Publication Status: Published online
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 Rev. Method: Peer
 Identifiers: DOI: 10.1021/cg3016707
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Title: Crystal Growth and Design
Source Genre: Journal
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Pages: - Volume / Issue: 13 (2) Sequence Number: - Start / End Page: 936 - 941 Identifier: -