English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
  Reactions involving fluoride ion. Part 41.1,2 Synthesis of hexakis(trifluoromethyl)cyclopentadiene and derived cyclopentadienide salts

Chambers, R., Gray, W., Vaughan, J., Korn, S., Medebielle, M., Batsanov, A., et al. (1997). Reactions involving fluoride ion. Part 41.1,2 Synthesis of hexakis(trifluoromethyl)cyclopentadiene and derived cyclopentadienide salts. Journal of the Chemical Society, Perkin Transactions 1, (2), 135-145. doi:10.1039/a604087j.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-BF49-0 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-BF4A-E
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Chambers, R.D.1, Author
Gray, W.K.1, Author
Vaughan, J.F.S.1, Author
Korn, S.R.2, Author
Medebielle, M3, Author
Batsanov, A.S.1, 4, Author
Lehmann, C.W.1, 4, 5, Author              
Howard, J.A.K.1, 4, Author
Affiliations:
1Department of Chemistry, University of Durham, South Road, Durham DH1 3LE, UK, ou_persistent22              
2Zeneca Specialties, PO Box A38, Leeds Road, Huddersfield, Yorkshire HD1 1FF, UK, ou_persistent22              
3Universite Denis Diderot, Laboratoire D’Electrochimie Molecularire, Place Jussieu, 75251 Paris, France, ou_persistent22              
4Chemical Crystallography Unit, University of Durham, South Road, Durham DH1 3LE, UK, ou_persistent22              
5Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

Content

show
hide
Free keywords: -
 Abstract: An efficient synthesis of hexakis(trifluoromethyl)cyclopentadiene 4, which shows a remarkably low reduction potential, is described. Various donors promote one-electron transfer to 4, leading to corresponding salts of pentakis(trifluoromethyl)cyclopentadienide 5. A novel approach to the synthesis of metal derivatives involves heating, or photolysis, of 4 directly with metals (including Cu, Ni, Fe and Co), leading to the corresponding ionic salts. X-Ray structural analysis was difficult because of rotation of trifluoromethyl groups in these salts, but structural data on 20, 24 and 30 has been obtained that reveals interesting conformations and stacking of the ions.

Details

show
hide
Language(s): eng - English
 Dates: 1997
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1039/a604087j
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Journal of the Chemical Society, Perkin Transactions 1
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: London : Royal Society of Chemistry
Pages: - Volume / Issue: (2) Sequence Number: - Start / End Page: 135 - 145 Identifier: ISSN: 1472-7781
CoNE: /journals/resource/111053443082010_1