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  Nitroso derivatives of 1,3-dithiol-2-ylidene stabilised by intramolecular oxygen...sulfur interactions: Synthesis and X-ray crystal structures

Bryce, M. R., Chalton, M. A., Batsanov, A. S., Lehmann, C. W., & Howard, J. A. K. (1996). Nitroso derivatives of 1,3-dithiol-2-ylidene stabilised by intramolecular oxygen..sulfur interactions: Synthesis and X-ray crystal structures. Journal of the Chemical Society-Perkin Transactions 2, (11), 2367-2371. doi:10.1039/p29960002367.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-BF45-7 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-11A6-A
Genre: Journal Article

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 Creators:
Bryce, Martin R.1, Author
Chalton, Michael A.1, Author
Batsanov, Andrei S.1, Author
Lehmann, Christian W.1, Author           
Howard, Judith A. K.1, Author
Affiliations:
1Department of Chemistry, University of Durham, South Road, Durham, DH1 3LE, UK, ou_persistent22              

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 Abstract: A series of 2-(nitrosomethylene)-1,3-dithiole derivatives 3 have been synthesised, and X-ray crystal structures of compounds 3g, 3h and 3I have been obtained. The coplanarity of the dithiole ring and the nitroso group in all three compounds favours π-conjugation, and short intramolecular oxygen ⋯ sulfur contacts (ca. 2.4 Å) occur between the nitrosyl oxygen and a sulfur atom of the dithiole ring; these structural features explain the stability and unreactivity of the series of compounds 3.

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Language(s): eng - English
 Dates: 1996-11-01
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/p29960002367
 Degree: -

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Title: Journal of the Chemical Society-Perkin Transactions 2
  Other : J. Chem. Soc.-Perkin Trans. 2
Source Genre: Journal
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Publ. Info: Cambridge, England : Royal Society of Chemistry
Pages: - Volume / Issue: (11) Sequence Number: - Start / End Page: 2367 - 2371 Identifier: ISSN: 1472-779X
CoNE: https://pure.mpg.de/cone/journals/resource/111053443082010