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  Floating Zone Single Crystal Growth of γ-CoV2O6 with Substantially Enhanced Crystal Size and Quality

Drees, Y., Agrestini, S., Zaharko, O., & Komarek, A. C. (2015). Floating Zone Single Crystal Growth of γ-CoV2O6 with Substantially Enhanced Crystal Size and Quality. Crystal Growth & Design, 15, 1168-1172. doi:10.1021/cg5015303.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-CBCA-4 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002E-9528-0
Genre: Journal Article

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 Creators:
Drees, Yvo1, Author           
Agrestini, Stefano2, Author           
Zaharko, Oksana3, Author
Komarek, Alexander Christoph4, Author           
Affiliations:
1Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863445              
2Stefano Agrestini, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863459              
3External Organizations, ou_persistent22              
4Alexander Komarek, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863446              

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 Abstract: Here, we report the growth of centimeter-sized ?-CoV2O6 single crystals by the optical floating zone method which are suitable for neutron scattering experiments. Our floating zone grown single crystals have higher magnetic ordering temperatures of 7.8 K, much more clearly visible magnetization plateaus, and substantially enhanced saturation magnetizations compared to flux-grown single crystals, which is also important with regard to the presence of orbital moment contributions within these S = 3/2 systems. Our centimeter-sized single crystals grown by the optical floating zone technique open the way toward the measurement of the peculiar magnetic properties of this intriguing system by means of elastic and inelastic neutron scattering and have been characterized by X-ray and neutron diffraction measurements.

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 Dates: 2015-01-252015-01-26
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: URI: http://dx.doi.org/10.1021/cg5015303
DOI: 10.1021/cg5015303
 Degree: -

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Title: Crystal Growth & Design
  Other : Cryst. Growth Des.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 15 Sequence Number: - Start / End Page: 1168 - 1172 Identifier: ISSN: 1528-7483
CoNE: https://pure.mpg.de/cone/journals/resource/110978984570353