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  Resolution of Diols via Catalytic Asymmetric Acetalization

Kim, J. H., Čorić, I., Palumbo, C., & List, B. (2015). Resolution of Diols via Catalytic Asymmetric Acetalization. Journal of the American Chemical Society, 137(5), 1778-1781. doi:10.1021/ja512481d.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0026-CE89-C Version Permalink: https://hdl.handle.net/21.11116/0000-0008-5091-9
Genre: Journal Article

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 Creators:
Kim, Ji Hye1, Author           
Čorić, Ilija1, Author           
Palumbo, Chiara1, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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 Abstract: A highly enantioselective kinetic resolution of diols via asymmetric acetalization has been achieved using a chiral confined imidodiphosphoric acid catalyst. The reaction is highly efficient for the resolution of tertiary alcohols, giving selectivity factors of up to >300. Remarkably, even in cases where the selectivity factors are only moderate, highly enantioenriched diols are obtained via a stereodivergent resolution to diastereomeric acetals.

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Language(s): eng - English
 Dates: 2014-12-082015-01-302015-02-11
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: ISI: 25636054
DOI: 10.1021/ja512481d
 Degree: -

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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 137 (5) Sequence Number: - Start / End Page: 1778 - 1781 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870