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  Two Manifolds for Metal-Catalyzed Intramolecular Diels-Alder Reactions of Unactivated Alkynes

Fürstner, A., & Stimson, C. C. (2007). Two Manifolds for Metal-Catalyzed Intramolecular Diels-Alder Reactions of Unactivated Alkynes. Angewandte Chemie International Edition, 46(46), 8845-8849. doi:10.1002/anie.200703321.

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z703321_s.pdf (Supplementary material), 153KB
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z703321_s.pdf
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Copyright Date:
2007
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Wiley-VCH, 69451 Weinheim, Germany
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 Creators:
Fürstner, Alois1, Author           
Stimson, Christopher C.1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: alkynes; copper; cycloaddition; gold; tandem reactions
 Abstract: Being unconventional: Although conventional metal-catalyzed [4+2] cycloadditions of inactivated dienynes are known to proceed by an oxidative cyclization/insertion mechanism, two entirely different pathways also result in formal Diels–Alder reactions (see scheme). These alternative mechanisms open new vistas for further functionalization of the products, as exemplified by an unprecedented cycloaddition/alkylation cascade.

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Language(s): eng - English
 Dates: 2007-07-242007-10-172007-11-26
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200703321
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 46 (46) Sequence Number: - Start / End Page: 8845 - 8849 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833