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  Unusual Structure and Reactivity of a Homoleptic "Super-Ate" Complex of Iron: Implications for Grignard Additions, Cross-Coupling Reactions, and the Kharasch Deconjugation

Fürstner, A., Krause, H., & Lehmann, C. W. (2006). Unusual Structure and Reactivity of a Homoleptic "Super-Ate" Complex of Iron: Implications for Grignard Additions, Cross-Coupling Reactions, and the Kharasch Deconjugation. Angewandte Chemie International Edition, 45(3), 440-444. doi:10.1002/anie.200502859.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0025-AE45-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-1979-6
Genre: Journal Article

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 Creators:
Fürstner, Alois1, Author           
Krause, Helga1, Author           
Lehmann, Christian W.2, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: ate complexes; cross-coupling; Grignard reaction; iron; single-electron transfer
 Abstract: The additional molecule of methyllithium present in [(Me4Fe)(MeLi)][Li(OEt2)]2 (1), the first structurally characterized ate complex of FeII bearing only alkyl substituents without any further stabilizing ligands (see picture: Fe: magenta; Li: cyan; O: red; C and H: gray), is a particularly remarkable structural feature and contributes to the fascinating reactivity profile of 1 in the title reactions.

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Language(s): eng - English
 Dates: 2005-08-112005-12-022006-01-09
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200502859
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 45 (3) Sequence Number: - Start / End Page: 440 - 444 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851