English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Magnetically Frustrated Double Perovskites: Synthesis, Structural Properties, and Magnetic Order of Sr2BOsO6 (B = Y, In, Sc)

Paul, A. K., Sarapulova, A., Adler, P., Reehuis, M., Kanungo, S., Mikhailova, D., et al. (2015). Magnetically Frustrated Double Perovskites: Synthesis, Structural Properties, and Magnetic Order of Sr2BOsO6 (B = Y, In, Sc). Zeitschrift für anorganische und allgemeine Chemie, 641(2), 197-205. doi:10.1002/zaac.201400590.

Item is

Files

show Files

Locators

show
hide
Locator:
Link (Any fulltext)
Description:
-
OA-Status:

Creators

show
hide
 Creators:
Paul, Avijit Kumar1, Author           
Sarapulova, Angelina1, Author           
Adler, Peter2, Author           
Reehuis, Manfred3, Author
Kanungo, Sudipta1, Author           
Mikhailova, Daria4, Author           
Schnelle, Walter5, Author           
Hu, Zhiwei6, Author           
Kuo, Changyang7, Author           
Siruguri, Vasudeva3, Author
Rayaprol, Sudhindra3, Author
Soo, Yunlian3, Author
Yan, Binghai8, Author           
Felser, Claudia9, Author           
Tjeng, Liu Hao10, Author           
Jansen, Martin11, Author           
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Peter Adler, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863435              
3External Organizations, ou_persistent22              
4Daria Mikhailova, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863448              
5Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              
6Zhiwei Hu, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863461              
7Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863445              
8Binghai Yan, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863427              
9Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863429              
10Liu Hao Tjeng, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863452              
11Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              

Content

show
hide
Free keywords: Double perovskite oxides, Antiferromagnetism, Magnetic frustration, Neutron diffraction
 Abstract: Double perovskites Sr2BOsO6 (B = Y, In, and Sc) were prepared from the respective binary metal oxides, and their structural, magnetic, and electronic properties were investigated. At room temperature all these compounds crystallize in the monoclinic space group P21/n. They contain magnetic osmium (Os5+, t2g3) ions and are antiferromagnetic insulators with Néel temperatures TN = 53 K, 26 K, and 92 K for B = Y, In, and Sc, respectively. Powder neutron diffraction studies on Sr2YOsO6 and Sr2InOsO6 showed that the crystal structures remain unchanged down to 3 K. The Y and In compounds feature a type I antiferromagnetic spin structure with ordered Os moments of 1.91 μB and 1.77 μB, respectively. The trend in TN does not simply follow the development of the lattice parameters, which suggests that d0 compared to d10 ions on the B site favor a somewhat different balance of exchange interactions in the frustrated Os5+ fcc-like lattice.

Details

show
hide
Language(s):
 Dates: 2015-02-032015-02-15
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/zaac.201400590
BibTex Citekey: ZAAC:ZAAC201400590
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 641 (2) Sequence Number: - Start / End Page: 197 - 205 Identifier: ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895