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  Aldehyde-Selective Wacker-Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co-Catalyst

Wickens, Z. K., Morandi, B., & Grubbs, R. H. (2013). Aldehyde-Selective Wacker-Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co-Catalyst. Angewandte Chemie International Edition, 52(43), 11257-11260. doi:10.1002/anie.201306756.

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 Creators:
Wickens, Zachary K.1, Author
Morandi, Bill1, 2, Author           
Grubbs, Robert H.1, Author
Affiliations:
1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125 (USA), ou_persistent22              
2Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              

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Free keywords: alkenes; anti-Markovnikov; oxidation; oxygen; palladium
 Abstract: Breaking the rules: Reversal of the high Markovnikov selectivity of Wacker-type oxidations was accomplished using a nitrite co-catalyst. Unbiased aliphatic alkenes can be oxidized with high yield and aldehyde selectivity, and several functional groups are tolerated. 18O-labeling experiments indicate that the aldehydic O atom is derived from the nitrite

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Language(s): eng - English
 Dates: 2013-09-132013-10-18
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201306756
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 52 (43) Sequence Number: - Start / End Page: 11257 - 11260 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833