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  Regioselective Wacker Oxidation of Internal Alkenes: Rapid Access to Functionalized Ketones Facilitated by Cross-Metathesis

Morandi, B., Wickens, Z. K., & Grubbs, R. H. (2013). Regioselective Wacker Oxidation of Internal Alkenes: Rapid Access to Functionalized Ketones Facilitated by Cross-Metathesis. Angewandte Chemie International Edition, 52(37), 9751-9754. doi:10.1002/anie.201303587.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0025-BA8A-7 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0025-BA8B-5
Genre: Journal Article

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 Creators:
Morandi, Bill1, 2, Author           
Wickens, Zachary K.1, Author
Grubbs, Robert H.1, Author
Affiliations:
1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125 (USA), ou_persistent22              
2Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              

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Free keywords: ketones; metathesis; oxidation; palladium; regioselectivity
 Abstract: Wacka wacka: The title reaction makes use of a wide range of directing groups (DG) to enable the highly regioselective oxidation of alkenes, and occurs predictably at the distal position. Both E and Z alkenes afford valuable functionalized ketones and cross-metathesis was shown to facilitate the

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Language(s): eng - English
 Dates: 2013-07-262013-09-09
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201303587
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 52 (37) Sequence Number: - Start / End Page: 9751 - 9754 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833