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  Iron-Catalyzed Cyclopropanation with Glycine Ethyl Ester Hydrochloride in Water

Morandi, B., Dolva, A., & Carreira, E. M. (2012). Iron-Catalyzed Cyclopropanation with Glycine Ethyl Ester Hydrochloride in Water. Organic Letters, 14(8), 2162-2163. doi:10.1021/ol300688p.

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 Creators:
Morandi, Bill1, 2, Author           
Dolva, Amund2, Author
Carreira, Erick M.2, Author
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              
2Laboratory of Organic Chemistry, ETH-Zürich, HCI H335, Wolfgang-Pauli-Strasse 10, 8093 Zürich, Switzerland, ou_persistent22              

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 Abstract: An iron-catalyzed cyclopropanation reaction of styrenes in aqueous media is disclosed that employs glycine ethyl ester hydrochloride in a tandem diazotization/cyclopropanation reaction. The products are accessed in good yields and good diastereoselectivity using readily available and inexpensive starting materials. Moreover, a wide range of transition metals may be used under these conditions, thus opening new opportunities for efficient carbene-transfer reactions under user-friendly conditions.

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Language(s): eng - English
 Dates: 2012-04-112012-04-20
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ol300688p
 Degree: -

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Title: Organic Letters
  Other : Org. Lett.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 14 (8) Sequence Number: - Start / End Page: 2162 - 2163 Identifier: ISSN: 1523-7060
CoNE: https://pure.mpg.de/cone/journals/resource/954925626338