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Free keywords:
cyclic ketones;
homologation;
synthetic methods;
trifluoromethyl ketones;
zirconium
Abstract:
A trifluoromethylated symphony! A new transformation involving trifluoromethyl diazomethane generated in situ has been developed that allows direct access to trifluoroethyl ketone derivatives from aldehyde and cyclohexanone compounds.