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  Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones

Morandi, B., & Carreira, E. M. (2011). Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones. Angewandte Chemie International Edition, 50(39), 9085-9088. doi:10.1002/anie.201103526.

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 Creators:
Morandi, Bill1, 2, Author           
Carreira, Erick M.2, Author
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              
2Laboratorium für Organische Chemie, ETH Zürich, 8093 Zürich (Switzerland) , ou_persistent22              

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Free keywords: cyclic ketones; homologation; synthetic methods; trifluoromethyl ketones; zirconium
 Abstract: A trifluoromethylated symphony! A new transformation involving trifluoromethyl diazomethane generated in situ has been developed that allows direct access to trifluoroethyl ketone derivatives from aldehyde and cyclohexanone compounds.

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Language(s): eng - English
 Dates: 2011-08-262011-09-19
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201103526
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 50 (39) Sequence Number: - Start / End Page: 9085 - 9088 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833