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  Iron-Catalyzed Preparation of Trifluoromethyl Substituted Vinyl- and Alkynylcyclopropanes

Morandi, B., Cheang, J., & Carreira, E. M. (2011). Iron-Catalyzed Preparation of Trifluoromethyl Substituted Vinyl- and Alkynylcyclopropanes. Organic Letters, 13(12), 3080-3081. doi:10.1021/ol200983s.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0026-A203-9 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0026-A204-7
Genre: Journal Article

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 Creators:
Morandi, Bill1, 2, Author           
Cheang, Jeremy2, Author
Carreira, Erick M.2, Author
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              
2Laboratorium für Organische Chemie, ETH Zürich, CH-8093 Zürich, Switzerland, ou_persistent22              

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 Abstract: A convenient iron-catalyzed procedure to prepare trifluoromethylated vinyl- and alkynylcyclopropanes in a chemo- and diastereoselective manner is presented. The active diazo compound (trifluoromethyl diazomethane) is generated in situ and used in the concomitant cyclopropanation reaction.

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Language(s): eng - English
 Dates: 2011-05-172011-06-03
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ol200983s
 Degree: -

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Title: Organic Letters
  Other : Org. Lett.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 13 (12) Sequence Number: - Start / End Page: 3080 - 3081 Identifier: ISSN: 1523-7060
CoNE: https://pure.mpg.de/cone/journals/resource/954925626338