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  Sr2MgOsO6: A Frustrated Os6+ (5d2) Double Perovskite with Strong Antiferromagnetic Interactions

Sarapulova, A., Adler, P., Schnelle, W., Mikhailova, D., Felser, C., Tjeng, L. H., et al. (2015). Sr2MgOsO6: A Frustrated Os6+ (5d2) Double Perovskite with Strong Antiferromagnetic Interactions. Zeitschrift für anorganische und allgemeine Chemie, 641(5), 769-771. doi:10.1002/zaac.201500151.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0026-B646-0 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-5158-B
Genre: Journal Article

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 Creators:
Sarapulova, Angelina1, Author              
Adler, Peter2, Author              
Schnelle, Walter3, Author              
Mikhailova, Daria4, Author              
Felser, Claudia5, Author              
Tjeng, Liu Hao6, Author              
Jansen, Martin7, Author              
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Peter Adler, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863435              
3Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              
4Daria Mikhailova, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863448              
5Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863429              
6Liu Hao Tjeng, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863452              
7Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              

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Free keywords: Double perovskite oxides, Osmium, Magnetic frustration, Antiferromagnetism, Spin-orbit coupling
 Abstract: The Os6+ (t2g2) double perovskite Sr2MgOsO6 was prepared as polycrystalline material from the respective binary metal oxides. Sr2MgOsO6 crystallizes with the tetragonal space group I4/m. Magnetization and specific heat measurements show a broad anomaly near 100 K, but no well-defined cusp. The magnetism is governed by strong antiferromagnetic interactions. Sr2MgOsO6 constitutes a new example for the peculiar, poorly understood magnetism of 5d2 ions on a frustrated fcc lattice, where spin-orbit coupling and orbital physics are expected to play an important role.

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Language(s): eng - English
 Dates: 2015-03-312015-04-14
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 641 (5) Sequence Number: - Start / End Page: 769 - 771 Identifier: ISSN: 0044-2313
CoNE: /journals/resource/954925453895