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  Butadiene from acetylene–ethylene cross-metathesis

Trotus, I.-T., Zimmermann, T., Duyckaerts, N., Geboers, J., & Schüth, F. (2015). Butadiene from acetylene–ethylene cross-metathesis. Chemical Communications, 51(33), 7124-7127. doi:10.1039/C5CC00853K.

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 Creators:
Trotus, Ioan-Teodor1, Author              
Zimmermann, Tobias1, Author              
Duyckaerts, Nicolas1, Author              
Geboers, Jan1, Author              
Schüth, Ferdi1, Author              
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1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              

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 Abstract: Acetylene to butadiene direct synthesis, via enyne cross-metathesis, is demonstrated with commercial ruthenium carbene catalysts. Using excess of ethylene, yields greater than 50% are obtained. High activity is observed in the first minute of the reaction (TOF > 800 h−1 based on butadiene). Catalyst reusability and poisoning are discussed.

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Language(s): eng - English
 Dates: 2015-03-182015-04-09
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C5CC00853K
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 51 (33) Sequence Number: - Start / End Page: 7124 - 7127 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413