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  Comparative investigations on a series of [hexakis(1-(tetrazol-1-yl) alkane-N4) iron(II)] bis(tetrafluoroborate) spin crossover complexes: Methyl- to butyl-substituted species

Hassan, N., Weinberger, P., Mereiter, K., Werner, F., Molnár, G. L., Bousseksou, A., et al. (2008). Comparative investigations on a series of [hexakis(1-(tetrazol-1-yl) alkane-N4) iron(II)] bis(tetrafluoroborate) spin crossover complexes: Methyl- to butyl-substituted species. Inorganica Chimica Acta, 361(5), 1291-1297. doi:10.1016/j.ica.2007.08.023.

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 Urheber:
Hassan, Nader1, Autor           
Weinberger, Peter1, Autor           
Mereiter, Kurt2, Autor           
Werner, Franz1, Autor           
Molnár, Gábor L.3, Autor           
Bousseksou, Azzedine3, Autor           
Valtiner, Markus1, Autor           
Linert, Wolfgang1, Autor           
Affiliations:
1Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-AC, A-1060 Vienna, Austria, ou_persistent22              
2Institute for Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9/164-SC, A-1060 Vienna, Austria, ou_persistent22              
3Laboratoire de Chimie de Coordination, LCC-CNRS UPR8241, 205 route de Narbonne, F-31077 Toulouse, France, ou_persistent22              

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Schlagwörter: Iron(II); Magnetic measurements; Spin crossover; Tetrazole; Vibrational spectroscopy
 Zusammenfassung: A series of 1-(tetrazol-1-yl)alkanes [ntz] with n = 1- 4 were synthesised as ligands for iron(II) spin crossover complexes. Within this series 1-(tetrazol-1-yl) butane [4tz] was prepared for the first time, whereas 1-(tetrazol-1-yl) methane [1tz], 1-(tetrazol-1-yl) ethane [2tz], 1-(tetrazol-1-yl) propane [3tz] and the [hexakis(ntz) iron(II)] bis(tetrafluoroborate)complexes were prepared according to the literature. Aiming for a comparative study we characterized all four compounds by XRPD, magnetic susceptibility measurements, Fe-57-Moessbauer spectroscopy and IR spectroscopy. [Fe(4tz)(6)](BF4)(2) yielded appropriate single crystals and an X-ray structure of the new compound [Fe(4tz)(6)](BF4)(2) is presented. The magnetic and structural properties of all [Fe(ntz)(6)](BF4)(2) are compared and discussed. (C) 2007 Elsevier B.V. All rights reserved.

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Sprache(n): eng - English
 Datum: 2008-04-01
 Publikationsstatus: Erschienen
 Seiten: 7
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: ISI: 000254858200011
DOI: 10.1016/j.ica.2007.08.023
 Art des Abschluß: -

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Titel: Inorganica Chimica Acta
  Kurztitel : Inorg. Chim. Acta
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: Amsterdam [etc.] : Elsevier
Seiten: - Band / Heft: 361 (5) Artikelnummer: - Start- / Endseite: 1291 - 1297 Identifikator: ISSN: 0020-1693
CoNE: https://pure.mpg.de/cone/journals/resource/954925622228_1