English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Intermetallic germanides with non-centrosymmetric structures derived from the Yb3Rh4Sn13 type

Gumeniuk, R., Schöneich, M., Kvashnina, K. O., Akselrud, L., Tsirlin, A. A., Nicklas, M., et al. (2015). Intermetallic germanides with non-centrosymmetric structures derived from the Yb3Rh4Sn13 type. Dalton Transactions, 44(12), 5638-5651. doi:10.1039/c4dt03155e.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0026-C029-5 Version Permalink: http://hdl.handle.net/21.11116/0000-0000-FF0F-2
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Gumeniuk, R.1, Author              
Schöneich, M.2, Author              
Kvashnina, K. O.3, Author
Akselrud, L.4, Author              
Tsirlin, A. A.4, Author              
Nicklas, M.5, Author              
Schnelle, W.6, Author              
Janson, O.7, Author              
Zheng, Q.4, Author              
Curfs, C.3, Author
Burkhardt, U.8, Author              
Schwarz, U.9, Author              
Leithe-Jasper, A.10, Author              
Affiliations:
1Roman Gumeniuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863421              
2Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
3External Organizations, ou_persistent22              
4Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
5Michael Nicklas, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863472              
6Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              
7Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863445              
8Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
9Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423              
10Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863406              

Content

show
hide
Free keywords: -
 Abstract: New germanides with composition RE3Pt4Ge13 (RE = Y, Pr, Sm, Gd, Tb, Tm) have been prepared by highpressure, high-temperature synthesis. Their crystal structures have been refined, and the relationship of this new rhombohedral and monoclinic structure types with the primitive cubic Yb3Rh4Sn13 prototype is discussed. Band structure calculations within density functional theory confirm the distorted rhombohedral and monoclinic structural arrangements to be energetically more favorable than the simple cubic one. X-ray absorption spectroscopy and magnetic susceptibility measurements indicate that the RE-atoms are in the +3 oxidation state in all studied compounds.

Details

show
hide
Language(s): eng - English
 Dates: 2015-02-232015-02-23
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000351439200041
DOI: 10.1039/c4dt03155e
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Dalton Transactions
  Other : Dalton Trans.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 44 (12) Sequence Number: - Start / End Page: 5638 - 5651 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323