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  Carbon Dioxide Activation and Reaction Induced by Electron Transfer at an Oxide-Metal Interface

Calaza, F., Stiehler, C., Fujimori, Y., Sterrer, M., Beeg, S., Ruiz Oses, M., et al. (2015). Carbon Dioxide Activation and Reaction Induced by Electron Transfer at an Oxide-Metal Interface. Angewandte Chemie International Edition, 54(42), 12484-12487. doi:10.1002/anie.201501420.

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 Creators:
Calaza, Florencia1, Author              
Stiehler, Christian1, Author              
Fujimori, Yuichi1, Author              
Sterrer, Martin1, 2, Author              
Beeg, Sebastian1, Author              
Ruiz Oses, Miguel1, Author              
Nilius, Niklas1, 3, Author              
Heyde, Markus1, Author              
Parviainen, Teemu4, Author
Honkala, Karoliina5, Author
Häkkinen, Hannu4, 5, Author
Freund, Hans-Joachim1, Author              
Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              
2Institute of Physics, University of Graz, 8010 Graz (Austria), ou_persistent22              
3Institute of Physics, Carl von Ossietzky Universität Oldenburg, 26111 Oldenburg (Germany), ou_persistent22              
4Department of Physics, Nanoscience Center, University of Jyväskylä, 40014 Jyväskylä (Finland), ou_persistent22              
5Department of Chemistry, Nanoscience Center, University of Jyväskylä, 40014 Jyväskylä (Finland), ou_persistent22              

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Free keywords: carbon dioxide; electron transfer; metal–insulator–metal structure; oxalate; oxygen
 Abstract: A model system has been created to shuttle electrons through a metal–insulator–metal (MIM) structure to induce the formation of a CO2 anion radical from adsorbed gas-phase carbon dioxide that subsequently reacts to form an oxalate species. The process is completely reversible, and thus allows the elementary steps involved to be studied at the atomic level. The oxalate species at the MIM interface have been identified locally by scanning tunneling microscopy, chemically by IR spectroscopy, and their formation verified by density functional calculations.

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Language(s): eng - English
 Dates: 2015-03-152015-02-122015-05-262015-10-12
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201501420
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 54 (42) Sequence Number: - Start / End Page: 12484 - 12487 Identifier: Other: 1433-7851
ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833