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  Synthesis and Crystal Structure of the Electron-Rich Cyano-Rhodate Ba3[Rh(CN)3]

Jach, F., Höhn, P., Prots, Y., & Ruck, M. (2015). Synthesis and Crystal Structure of the Electron-Rich Cyano-Rhodate Ba3[Rh(CN)3]. Zeitschrift für anorganische und allgemeine Chemie, 641, 998-1001. doi:10.1002/zaac.201500122.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-A4E7-4 Version Permalink: http://hdl.handle.net/21.11116/0000-0000-FFED-7
Genre: Journal Article

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 Creators:
Jach, Franziska1, Author              
Höhn, Peter2, Author              
Prots, Yurii3, Author              
Ruck, Michael4, Author              
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Peter Höhn, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863419              
3Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
4Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

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 Abstract: Brownish gray microcrystalline powders of Ba-3[Rh(CN)(3)] were synthesized from pellets of mixtures of Ba2N, rhodium, NaCN, and graphite at 1070 K in an argon atmosphere. Synchrotron powder diffraction data at 293(1) K revealed the crystal structure of the compound [P6(3)/m, a = 9.23266(7) angstrom, c = 5.81612(6) angstrom] is isostructural to Ba-3[Co(CN)(3)] and Ba-3[Ir(CN)(3)]. The trigonal-planar complex [Rh(CN)(3)](6-) is surrounded by nine Ba2+ cations forming a tri-capped trigonal prism. Compared to typical cyano ligands, the C-N bond is long [1.21(5) angstrom] and the vibrational frequencies are low (IR 1674 cm(-1), Raman 1728 cm(-1)).

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Language(s): eng - English
 Dates: 2015-05-022015-05-02
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000355245000002
DOI: 10.1002/zaac.201500122
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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 641 Sequence Number: - Start / End Page: 998 - 1001 Identifier: ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895