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  Catalytic Asymmetric α-Amination of α-Branched Ketones via Enol Catalysis

Shevchenko, G. A., Pupo, G., & List, B. (2015). Catalytic Asymmetric α-Amination of α-Branched Ketones via Enol Catalysis. Synlett, 26(10), 1413-1416. doi:10.1055/s-0034-1380680.

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 Creators:
Shevchenko, Grigory A.1, Author              
Pupo, Gabriele1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: asymmetric synthesis; Brønsted acid catalysis; electrophilic amination; α-branched ketones; enol catalysis; azodicarboxylates
 Abstract: We report a highly enantioselective α-amination of α-branched ketones catalyzed by a chiral phosphoric acid employing azodicarboxylates as reagents. The desired products were obtained in good to excellent yields and enantioselectivities.

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Language(s): eng - English
 Dates: 2015-03-092015-04-232015-06-16
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0034-1380680
 Degree: -

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Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 26 (10) Sequence Number: - Start / End Page: 1413 - 1416 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856