English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  A simple model for heteronuclear spin decoupling in solid-state NMR

Ernst, M., Zimmermann, H., & Meier, B. H. (2000). A simple model for heteronuclear spin decoupling in solid-state NMR. Chemical Physics Letters, 317(6), 581-588. doi:10.1016/S0009-2614(99)01423-2.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-D09D-3 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-D09E-1
Genre: Journal Article
Alternative Title : A simple model for heteronuclear spin decoupling in solid-state NMR

Files

show Files
hide Files
:
ChemPhysLett_317_2000_581.pdf (Any fulltext), 330KB
 
File Permalink:
-
Name:
ChemPhysLett_317_2000_581.pdf
Description:
-
OA-Status:
Visibility:
Restricted (Max Planck Institute for Medical Research, MHMF; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Creators

show
hide
 Creators:
Ernst, Matthias, Author
Zimmermann, Herbert1, Author           
Meier, Beat H., Author
Affiliations:
1Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497712              

Content

show
hide
Free keywords: -
 Abstract: We propose a simple model to describe heteronuclear spin decoupling in solid−state NMR under magic−angle sample spinning (MAS). It is based on a coherent description of two heteronuclear dipolar−coupled spins (I and S) and an incoherent description of the interaction of the I−spin with a large number of other I−spins. The abundant and strongly coupled I−spins are irradiated. The selected I−spin is coupled by a spin−diffusion type superoperator to the I−spin bath, and this coupling is described by a single spin−diffusion rate constant. Such a model allows us to simulate efficiently the behavior of a spin system under heteronuclear decoupling in the case of CW irradiation as well as in the case of phase−modulated sequences such as TPPM

Details

show
hide
Language(s): eng - English
 Dates: 1999-09-301999-12-102000-02-142000-02-11
 Publication Status: Issued
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 666365
DOI: 10.1016/S0009-2614(99)01423-2
URI: http://www.sciencedirect.com/science/article/pii/S0009261499014232
Other: 4666
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Chemical Physics Letters
  Other : Chem. Phys. Lett.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Amsterdam : North-Holland
Pages: - Volume / Issue: 317 (6) Sequence Number: - Start / End Page: 581 - 588 Identifier: ISSN: 0009-2614
CoNE: https://pure.mpg.de/cone/journals/resource/954925389241