The radiative lifetime of metastable CO (a (3)Pi, v=0).

Gilijamse, J. J.; Hoekstra, S.; Meek, S. A.; Metsala, M.; van de Meerakker, S. Y. T.; Meijer, G.; Groenenboom, G. C.

doi:10.1063/1.2813888

Local TagsRelease HistoryDetailsSummary

The radiative lifetime of metastable CO (a (3)Pi, v=0).

Gilijamse, J. J., Hoekstra, S., Meek, S. A., Metsala, M., van de Meerakker, S. Y. T., Meijer, G., et al. (2007). The radiative lifetime of metastable CO (a (3)Pi, v=0). Journal of Chemical Physics, 127(22): 221102. doi:10.1063/1.2813888.

Item is Released

show all hide all

Basic

show hide

Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-D31D-F Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0028-9479-4

Genre: Journal Article

Files

show Files

hide Files

:

2172847.pdf (Publisher version), 630KB

View Save

File Permalink:
https://hdl.handle.net/11858/00-001M-0000-0027-D31F-B

Name:
2172847.pdf

Description:
-

OA-Status:

Visibility:
Public

MIME-Type / Checksum:
application/pdf / [MD5]

Technical Metadata:

View

Copyright Date:
-

Copyright Info:
-

License:
-

Locators

show

hide

Locator:
http://scitation.aip.org/deliver/fulltext/aip/journal/jcp/127/22/1.2813888.pdf;jsessionid=21u3bd7et1ot7.x-aip-live-06?itemId=/content/aip/journal/jcp/127/22/10.1063/1.2813888&mimeType=pdf&containerItemId=content/aip/journal/jcp (Publisher version) Open Access status unknown

Description:
-

OA-Status:

Creators

show

hide

Creators:
Gilijamse, J. J., Author
Hoekstra, S., Author
Meek, S. A.¹, Author
Metsala, M., Author
van de Meerakker, S. Y. T., Author
Meijer, G., Author
Groenenboom, G. C., Author

Affiliations:
1Research Group of Precision Infrared Spectroscopy, MPI for Biophysical Chemistry, Max Planck Society, ou_2149674

Content

show

hide

Free keywords: -

Abstract: We present a combined experimental and theoretical study on the radiative lifetime of CO in the a (3)Pi(1,2), v=0 state. CO molecules in a beam are prepared in selected rotational levels of this metastable state, Stark-decelerated, and electrostatically trapped. From the phosphorescence decay in the trap, the radiative lifetime is measured to be 2.63 +/- 0.03 ms for the a (3)Pi(1), v=0, J=1 level. From the spin-orbit coupling between the a (3)Pi and the A (1)Pi states a 20% longer radiative lifetime of 3.16 ms is calculated for this level. It is concluded that coupling to other (1)Pi states contributes to the observed phosphorescence rate of metastable CO. (c) 2007 American Institute of Physics.

Details

show

hide

Language(s): eng - English

Dates: Date issued: 2007-12-14

Publication Status: Issued

Pages: -

Publishing info: -

Table of Contents: -

Rev. Type: Peer

Identifiers: DOI: 10.1063/1.2813888

Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show

hide

Title: Journal of Chemical Physics

Source Genre: Journal

Creator(s):

Affiliations:

Publ. Info: -

Pages: 4 Volume / Issue: 127 (22) Sequence Number: 221102 Start / End Page: - Identifier: -