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  ThPt2: A New Representative of Close Packed Tetragonal Structures.

Gumeniuk, R., Schnelle, W., Burkhardt, U., Borrmann, H., Nicklas, M., Ormeci, A., et al. (2015). ThPt2: A New Representative of Close Packed Tetragonal Structures. Inorganic Chemistry, 54(13), 6338-6346. doi:10.1021/acs.inorgchem.5b00669.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-F87A-4 Version Permalink: http://hdl.handle.net/21.11116/0000-0001-177D-A
Genre: Journal Article

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 Creators:
Gumeniuk, Roman1, Author              
Schnelle, Walter2, Author              
Burkhardt, Ulrich3, Author              
Borrmann, Horst4, Author              
Nicklas, Michael5, Author              
Ormeci, Alim6, Author              
Kohout, Miroslav7, Author              
Leithe-Jasper, Andreas8, Author              
Grin, Yuri9, Author              
Affiliations:
1Roman Gumeniuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863421              
2Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              
3Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
4Horst Borrmann, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863410              
5Michael Nicklas, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863472              
6Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
7Miroslav Kohout, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863417              
8Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863406              
9Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              

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 Abstract: ThPt2 crystallizes with unique type of structure (space group I4/mmm, a = 4.1565(1) A, c = 14.3663(7) A, Pearson symbol tI12), which belongs to the group of the close packed tetragonal structures. An analysis of the chemical bonding by the electron localizability approach reveals the formation of two-dimensional layered platinum anionic substructures interlinked by strongly polar bonds to Th. Measurements of magnetic susceptibility, electrical resistivity, and specific heat show ThPt2 to be diamagnetic with metallic type of electrical conductivity in good agreement with the calculated electronic structure (N(EF) = 0.9 states eV(-1) f.u.(-1)).

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Language(s): eng - English
 Dates: 2015-06-232015-06-23
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 26102602
DOI: 10.1021/acs.inorgchem.5b00669
 Degree: -

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Title: Inorganic Chemistry
  Abbreviation : Inorg. Chem.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 54 (13) Sequence Number: - Start / End Page: 6338 - 6346 Identifier: ISSN: 0020-1669
CoNE: /journals/resource/0020-1669