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  Dihalo(imidazolium)sulfuranes: A Versatile Platform for the Synthesis of New Electrophilic Group-Transfer Reagents

Talavera, G., Peña, J., & Alcarazo, M. (2015). Dihalo(imidazolium)sulfuranes: A Versatile Platform for the Synthesis of New Electrophilic Group-Transfer Reagents. Journal of the American Chemical Society, 137(27), 8704-8707. doi:10.1021/jacs.5b05287.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0028-184E-1 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0028-184F-0
Genre: Journal Article

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 Creators:
Talavera, Garazi1, Author           
Peña, Javier1, Author           
Alcarazo, Manuel1, Author           
Affiliations:
1Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              

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 Abstract: The syntheses of imidazolium thiocyanates and imidazolium thioalkynes from dihalo(imidazolium) sulfuranes are reported and their reactivities as CN+ and R-CC+ synthons evaluated, respectively. The easy and scalable preparation of these electrophilic reagents, their operationally simple handling, broad substrate scope, and functional group tolerance clearly illustrate the potential of these species to become a reference for the direct electrophilic cyanation and alkynylation of organic substrates.

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Language(s): eng - English
 Dates: 2015-05-212015-07-012015-07-15
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jacs.5b05287
 Degree: -

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Title: Journal of the American Chemical Society
  Other : J. Am. Chem. Soc.
  Abbreviation : JACS
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 137 (27) Sequence Number: - Start / End Page: 8704 - 8707 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870