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  Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents

Haldón, E., Kozma, Á., Tinnermann, H., Gu, L., Goddard, R., & Alcarazo, M. (2016). Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents. Dalton Transactions, 45(5), 1872-1876. doi:10.1039/C5DT02341F.

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 Creators:
Haldón, Estella1, Author              
Kozma, Ágnes1, Author              
Tinnermann, Hendrik1, Author              
Gu, Lianghu1, Author              
Goddard, Richard2, Author              
Alcarazo, Manuel1, Author              
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1Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: Mono- and dicationic phosphines have been synthesized through the reaction of chloroimidazolinium or chloroamidinium salts with secondary or primary phosphines respectively. The resulting ligands, which depict a significantly reduced donor ability compared with their neutral analogues, have been used to design Pt(II) and Au(I) complexes that effectively catalyse the hydroarylation of alkynes.

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Language(s): eng - English
 Dates: 2015-06-192015-07-062015-07-152016-02-07
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C5DT02341F
 Degree: -

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Title: Dalton Transactions
  Other : Dalton Trans.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 45 (5) Sequence Number: - Start / End Page: 1872 - 1876 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323